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METHANOL 2000

NIOSH Manual of Analytical Methods (NMAM), Fourth EditionMETHANOL2000CH3OH MW: CAS: 67-56-1 RTECS: PC1400000 METHOD: 2000 , Issue 3 EVALUATION: FULL Issue 1: 15 August 1984 Issue 3: 15 January 1998 OSHA : 200 ppmNIOSH: 200 ppm (skin); STEL 250 ppm (skin) ACGIH: 200 ppm (skin); STEL 250 ppm (skin)(1 ppm = mg/m3 @ NTP)PROPERTIES:liquid; d = g/ml @ 20 C; BP = C;VP = kPa (115 mm Hg; v/v) @ 20C; explosive range is 6 to 36% (v/v) in airSYNONYMS: Methyl alcohol, wood alcohol, carbinol, wood naphtha, wood spirit SAMPLINGMEASUREMENTSAMPLER:SOLID SORBENT TUBE(silica gel, 100/50 mg)FLOW to L/minVOL-MIN:1 L @ 200 ppm -MAX:5 LSHIPMENT:pack securely for shipment; store at STABILITY :at least 30 days at 5C [1]BLANKS:2 to 10 field blanks per setTECHNIQUE:GAS CHROMATOGRAPHY, FIDANALYTE:methanolDESORPTION:1 mL water/isopropanol (95:5) [1]INJECTION VOLUME:1 L TEMPERATURE- INJECTION:250 C-DETECTOR:300 C -COLUMN:50 to 90 C (8 C/min) [1](Split Ratio 10:1)CARRIER GAS:He, mL/minCOLUMN:capillary, 30 m x ID; 3- m film35% diph

However, any compound with a similiar retention time may interfere. Positive identification can be confirmed by dual column chromatography with a 100% PEG capillary column. Mass spectrometry can also be used as a confirmation aid. OTHER METHODS: This method updates and replaces NMAM 2000 (August 15, 1994), which combined and replaced Method S59

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