Surface Chemistry

Surface Chemistry deals with phenomena that occurat the surfaces or interfaces. The interface or surfaceis represented by separating the bulk phases by ahyphen or a slash. For example, the interface betweena solid and a gas may be represented by solid-gasor solid/gas. Due to complete miscibility, there is nointerface between the gases. The bulk phases thatwe come across in Surface Chemistry may be purecompounds or solutions. The interface is normally afew molecules thick but its area depends on the sizeof the particles of bulk phases. Many importantphenomena, noticeable amongst these beingcorrosion, electrode processes, heterogeneouscatalysis, dissolution and crystallisation occur atinterfaces.

(iv) Surface area of adsorbent: The extent of adsorption increases with the increase of surface area of the adsorbent. Thus, finely divided metals and porous substances having large surface areas are good adsorbents. (v) Enthalpy of adsorption: No doubt, physical adsorption is an exothermic process but its enthalpy of adsorption is quite low (20–

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  Surfaces, Process, Chemistry, Surface chemistry, Adsorption

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