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Table of Contents - Polyurethane Raw Materials

1 Table of Contents 1. Emergency Contact Numbers .. 2 2. Introduction .. 3 3. MDI Products .. 5 MDI Production Process .. 5 MDI Product Family, Properties, and Applications .. 6 4. Health Considerations .. 9 Acute Hazards .. 9 Effects on Respiratory System .. 9 Effects on Eyes, Skin and Ingestion .. 10 Chronic Hazards .. 10 Sensitization .. 10 First Aid .. 10 Medical Considerations .. 11 Industrial Hygiene .. 11 5. Safe Handling of MDI Products .. 13 Employee Training and 13 Engineering Considerations .. 13 Personal Protective Equipment .. 14 Fire Hazards .. 15 6. Shipment of MDI Products .. 16 Regulations .. 16 Shipping Containers .. 16 Unloading Operations .. 17 Bulk Unloading .. 17 Drum Handling .. 17 Sample Shipments .. 17 7. Storage .. 19 Storage and Handling Considerations .. 19 Storage Tank Design .. 19 Container Storage .. 20 8. Emergency Procedures .. 21 Guidelines for Dealing with MDI Product Incidents.

presence of catalysts/basic materials, the reaction becomes progressively more vigorous and can become violent. The reaction of MDI with water liberates CO 2 gas and forms insoluble polyurea compounds. These polyurea products often take the form of globules with liquid isocyanate and CO2 trapped inside. These globules can float due to the ...

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