Ion chromatography analysis methods and issues
Depending on the sample matrix, other ions influence solubility. K sp = [A-][C+] pK sp = -log K sp [AC] Example: Analysis of Cl in a sample matrix containing Ag, or Analysis of SO 4 in a sample with high Ca. K sp for AgCl is 9.75 implying that Cl is not in solution K sp for CaSO 4 is 5.04 implying that only a portion of the SO
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