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SAFETY DATA SHEET (SDS) BENZENE 1. Identification

Revised 2 on 11/2/2015. SAFETY DATA SHEET (SDS). BENZENE . 1. Identification SDS Record Number : PCS 95004. Date of SDS : 11 February 2015. Identity of the substance : BENZENE Product Description : Aromatic hydrocarbon. Other names/synonyms : Benzol, Phenyl hydride, BENZENE and mixtures having 10%. BENZENE or more (IBC code). Name of the supplier : Petrochemical Corporation of Singapore (Private) Limited Recommended uses : Chemical feedstock. Contact detail of the supplier : 100 Ayer Merbau Road, Singapore 628277. : +65 68672102. 24-Hour Emergency contact : Asia Pacific +65 3158 1074 (Singapore). China +86 10 5100 3039 (Beijing). Europe, Israel & Americas +44 (0) 1235 239 670 (UK). Middle East & Africa +44 (0) 1235 239 671 (UK).

> 1,000 ppm or unknown concentration (1) Self-contained breathing apparatus with full facepiece in positive-pressure mode; or (2) Full-facepiece positive-pressure supplied-air respirator with auxiliary self-contained air supply. Escape (1) Any organic vapor gas mask; or (2) Any self-contained breathing apparatus with full facepiece.

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Transcription of SAFETY DATA SHEET (SDS) BENZENE 1. Identification

1 Revised 2 on 11/2/2015. SAFETY DATA SHEET (SDS). BENZENE . 1. Identification SDS Record Number : PCS 95004. Date of SDS : 11 February 2015. Identity of the substance : BENZENE Product Description : Aromatic hydrocarbon. Other names/synonyms : Benzol, Phenyl hydride, BENZENE and mixtures having 10%. BENZENE or more (IBC code). Name of the supplier : Petrochemical Corporation of Singapore (Private) Limited Recommended uses : Chemical feedstock. Contact detail of the supplier : 100 Ayer Merbau Road, Singapore 628277. : +65 68672102. 24-Hour Emergency contact : Asia Pacific +65 3158 1074 (Singapore). China +86 10 5100 3039 (Beijing). Europe, Israel & Americas +44 (0) 1235 239 670 (UK). Middle East & Africa +44 (0) 1235 239 671 (UK).

2 2. Hazards Identification GHS Classification Hazard Class Hazard Category Flammable Liquid 2. Acute Toxicity (Oral) 4. Skin Corrosion/Irritation 2. Serious Eye Damage/ Irritation 2A. Germ Cell Mutagenicity 2. Toxic to reproduction 2. Carcinogenicity 1A. STOST (Single exposure) 1 (respiratory organs). STOST (Single exposure) 3 (narcotic effects). STOST (Repeated exposure) 1 (central nervous system, hematopoietic organs). Aspiration hazard 1. Acute hazards to the aquatic environment 2. Pictograms Signal Word: Danger Hazard Statements Highly Flammable liquid and vapour Harmful if swallowed Causes skin irritation Causes serious eye irritation Suspected of causing genetic defects BENZENE SDS. Page 1 of 11.

3 Revised 2 on 11/2/2015. Suspected of damaging fertility or the unborn child May cause cancer Causes damage to organs May cause drowsiness or dizziness Causes damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Toxic to aquatic life Precautionary Statements Prevention Keep container tightly closed. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Wear protective gloves/protective clothing/eye protection/face protection Ground/Bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary measures against static discharge. Use only non-sparking tools. Wash thoroughly after handling.

4 Obtain special instructions before use. Do not handle until all SAFETY precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment Use only outdoors or in well-ventilated area. Response IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/ shower. IF exposed: Call a POISON CENTER/doctor/physician. In case of fire: Use appropriate media for extinction. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash before re-use. If skin irritation occurs, seek medical advice/attention.

5 Take of contaminated clothing and wash before re-use. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. IF exposed or concerned: Get medical attention/advice. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician. if you feel unwell. Storage Store in a well-ventilated place. Keep cool. Store locked up. Store container in a well-ventilated place. Keep container tightly closed. Disposal Dispose of the contents/container in accordance to the local mandatory rules and regulations BENZENE SDS.

6 Page 2 of 11. Revised 2 on 11/2/2015. 3. Composition/Information On Ingredients Chemical Identification : C6H6. Common name(s) / synonym(s) : BENZENE , Bicarburet of hydrogen, carbon oil, coal naphtha, cyclohexatriene, mineral naphtha, phenyl hydride, pyrobenzol CAS number / EC number : 71-43-2 /601-020-00-8. 4. First-Aid Measures Eye: Irrigate immediately. If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper lids. Get medical attention immediately. Skin: Soap wash immediately. If this chemical contacts the skin, immediately wash the contaminated skin with soap and water. If this chemical penetrates the clothing, immediately remove the clothing, wash the skin with soap and water, and get medical attention promptly.

7 Breathing: Respiratory support. If a person breathes large amounts of this chemical, move the exposed person to fresh air at once. If breathing has stopped, perform artificial resuscitation. Keep the affected person warm and at rest. Get medical attention as soon as possible. Swallow: Medical attention immediately. If this chemical has been swallowed, get medical attention immediately. Do not induce vomiting. Keep at rest. 5. Fire-Fighting Measures Extinguishing media: Water spray, foam or dry chemical based on situation. Small Fires Dry chemical, CO2, water spray or regular foam. Large Fires Water spray, fog or regular foam. Do not use straight streams. Move containers from fire area if you can do it without risk.

8 Fire involving Tanks or Car/Trailer Loads Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting SAFETY devices or discoloration of tank. Always stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if impossible, withdraw from area and let fire burn. Specific hazards arising from the chemical: This is a Flammable Liquid and may release vapours that form flammable mixtures at or above the flash point. BENZENE SDS. Page 3 of 11. Revised 2 on 11/2/2015. Special protective equipment and precautions for fire fighters: Use water spray to cool fire exposed surfaces and to protect personnel.

9 Shut off fuel to fire if possible to do so without hazard. If a leak or spill has not ignited use water spray to disperse the vapours. Either allow fire to burn out under controlled conditions or extinguish with foam or dry chemical. Try to cover liquid spills with foam. A self-contained breathing apparatus (SCBA) is recommended for indoor fires and any significant outdoor fires. For small outdoor fires, which may easily be extinguished with a portable fire extinguisher, use of an SCBA is optional. Caution: All these products have a very low flash point: Use of water spray when fighting fire may be inefficient. 6. Accidental Release Measures Call Emergency Response Telephone Number on Shipping Paper first.

10 If Shipping Paper not available or no answer, refer to appropriate telephone number. As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet). in all directions. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. Remove all ignition sources. Dike far ahead of liquid spill for later disposal. Water spray may reduce vapor; but may not prevent ignition in closed spaces. Warn occupants and shipping in downwind areas of fire and explosion hazard and request all to stay clear. Collect leaking and spilled liquid in sealable containers as far as possible. Prevent additional discharge of material, if possible to do so without hazard.


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