Page 1/9 Safety Data Sheet - Agilent

1 Page 1/10 Safety data Sheetacc. to OSHA HCSP rinting date 02/19/2021 Reviewed on 02/19 Identification Product identifier Product name:Aluminum Standard: 1000 g/mL Al in 5% HNO3 [500ml bottle] Part number:5190-8243 Application of the substance / the mixtureReagents and Standards for Analytical Chemical Laboratory Use Details of the supplier of the Safety data Sheet Manufacturer/Supplier: Agilent Technologies, Inc. Tel: 800-227-97705301 Stevens Creek BlvdSanta Clara, CA 95051,USA Information department:e-mail: Emergency telephone number:CHEMTREC : 1-800-424-93002 Hazard(s) identification Classification of the substance or mixtureGHS05 CorrosionMet. H290 May be corrosive to Dam. 1 H318 Causes serious eye Irrit. 2 H315 Causes skin irritation. Label elements GHS label elementsThe product is classified and labeled according to the Globally Harmonized System (GHS).

2 Hazard pictogramsGHS05 Signal wordDanger Hazard-determining components of labeling:nitric acid Hazard statementsH290 May be corrosive to Causes skin Causes serious eye damage. Precautionary statementsP280 Wear protective gloves / eye protection / face +P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue call a poison center/doctor.(Contd. on page 2) US Page 2/10 Safety data Sheetacc. to OSHA HCSP rinting date 02/19/2021 Reviewed on 02/19/2021 Product name:Aluminum Standard: 1000 g/mL Al in 5% HNO3 [500ml bottle](Contd. of page 1) treatment (see on this label).P332+P313If skin irritation occurs: Get medical in corrosive resistant container with a resistant inner liner. Classification system: NFPA ratings (scale 0 - 4)300 Health = 3 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY300 Health = 3 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT:Not applicable.

3 VPvB:Not Composition/information on ingredients Chemical characterization: Mixtures Description:Aqueous contains substances at levels not considered to be hazardous. Dangerous components:CAS: 7697-37-2 RTECS: QU5775000nitric acid Ox. Liq. 3, H272; Acute Tox. 3, H331; Met. , H290; Skin , H314<5% Additional information:The concentration of the acid stated in this SDS is calculated as an absolute mass concentration (%w/v). Thisis less than the acid concentration stated on the product label and COA, which reflects a percent value of thecommercially available concentrated aqueous form of the First-aid measures Description of first aid measures General information:Immediately remove any clothing soiled by the product. After inhalation:Supply fresh air; consult doctor in case of complaints. After skin contact:Immediately wash with water and soap and rinse skin irritation continues, consult a doctor.

4 After eye contact:Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing:Rinse mouth. Do not induce vomiting. Information for doctor: Most important symptoms and effects, both acute and delayedNo further relevant information available.(Contd. on page 3) US Page 3/10 Safety data Sheetacc. to OSHA HCSP rinting date 02/19/2021 Reviewed on 02/19/2021 Product name:Aluminum Standard: 1000 g/mL Al in 5% HNO3 [500ml bottle](Contd. of page 2) Indication of any immediate medical attention and special treatment neededNo further relevant information Fire-fighting measures Extinguishing media Suitable extinguishing agents:Use fire fighting measures that suit the environment. Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in case of fire. Advice for firefighters Protective equipment:Wear self-contained respiratory protective Accidental release measures Personal precautions, protective equipment and emergency proceduresWear protective equipment.

5 Keep unprotected persons away. Environmental precautions:Dilute with plenty of not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up:Use neutralizing contaminated material as waste according to item liquid components with liquid-binding NOT USE SAWDUST. Reference to other sectionsSee Section 7 for information on safe Section 8 for information on personal protection Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1:CAS: 7697-37-2 nitric ppmCAS: 7784-27-2 Aluminium nitrate nonahydrate83 mg/m PAC-2:CAS: 7697-37-2 nitric acid24 ppmCAS: 7784-27-2 Aluminium nitrate nonahydrate920 mg/m PAC-3:CAS: 7697-37-2 nitric acid92 ppmCAS: 7784-27-2 Aluminium nitrate nonahydrate5,500 mg/m 7 Handling and storage Handling: Precautions for safe handlingStore in cool, dry place in tightly closed receptacles.

6 Information about protection against explosions and fires:No special measures required.(Contd. on page 4) US Page 4/10 Safety data Sheetacc. to OSHA HCSP rinting date 02/19/2021 Reviewed on 02/19/2021 Product name:Aluminum Standard: 1000 g/mL Al in 5% HNO3 [500ml bottle](Contd. of page 3) Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles:Please refer to the manufacturers certificate for specific storage and transport temperature only in the original receptacle unless other advice is given on the container in a well-ventilated place. Keep away from sources of ignition and heat. Information about storage in one common storage facility:Store away from foodstuffs. Further information about storage conditions:Keep receptacle tightly sealed. Specific end use(s)No further relevant information Exposure controls/personal protection Additional information about design of technical systems:No further data ; see item 7.

7 Control parameters Components with limit values that require monitoring at the workplace:CAS: 7697-37-2 nitric acidPEL Long-term value: 5 mg/m , 2 ppmREL Short-term value: 10 mg/m , 4 ppmLong-term value: 5 mg/m , 2 ppmTLV Short-term value: 10 mg/m , 4 ppmLong-term value: mg/m , 2 ppm Additional information:The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures:Keep away from foodstuffs, beverages and remove all soiled and contaminated hands before breaks and at the end of contact with the contact with the eyes and skin. Breathing equipment:Not suitable respiratory protective device in case of insufficient ventilation. Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the of the glove material on consideration of the penetration times, rates of diffusion and thedegradationThe protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and therelated standard EN374 Protective gloves Material of glovesPVC glovesNeoprene gloves(Contd.)

8 On page 5) US Page 5/10 Safety data Sheetacc. to OSHA HCSP rinting date 02/19/2021 Reviewed on 02/19/2021 Product name:Aluminum Standard: 1000 g/mL Al in 5% HNO3 [500ml bottle](Contd. of page 4) Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to beobserved. Eye protection:Tightly sealed goggles9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance:Form:LiquidColor:Colorless Odor:Odorless Odor threshold:Not determined. pH-value:<2 Change in conditionMelting point/Melting range:0 C (32 F)Boiling point/Boiling range:100 C (212 F) Flash point:Not applicable. Flammability (solid, gaseous):Not determined. Ignition temperature:Not determined Decomposition temperature:Not determined. Auto igniting:Product is not selfigniting.

9 Danger of explosion:Not determined. Explosion limits:Lower:Not :Not determined. Vapor pressure at 20 C (68 F):23 hPa ( mm Hg) Density at 20 C (68 F) g/cm ( lbs/gal) Relative densityNot determined. Vapor densityNot determined. Evaporation rateNot determined. Solubility in / Miscibility withWater:Fully miscible. Partition coefficient (n-octanol/water):Not determined. Viscosity:Dynamic at 20 C (68 F) mPasKinematic:Not determined.(Contd. on page 6) US Page 6/10 Safety data Sheetacc. to OSHA HCSP rinting date 02/19/2021 Reviewed on 02/19/2021 Product name:Aluminum Standard: 1000 g/mL Al in 5% HNO3 [500ml bottle](Contd. of page 5) Other informationNo further relevant information Stability and reactivity ReactivityStable under normal further relevant information available. Chemical stabilityStable under normal conditions. Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.

10 Possibility of hazardous reactionsNo dangerous reactions known. Conditions to avoidHeat. Incompatible materials:Strong oxidizing Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification:CAS: 7697-37-2 nitric acidInhalative LC50/4 h mg/l (rat) Primary irritant effect: on the skin:Irritant to skin and mucous membranes. on the eye:Strong irritant with the danger of severe eye injury. Sensitization:Based on available data , the classification criteria are not met. Additional toxicological information:The product shows the following dangers according to internally approved calculation methods forpreparations:Irritant Carcinogenic categories IARC (International Agency for Research on Cancer)None of the ingredients is listed.