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Coordination Chemistry II: Ligand Field Theory Continued

Coordination Chemistry II: Ligand Field Theory Continued

www.chem.uci.edu

Tetrahedral Crystal Field Splitting barycenter (spherical field) t 2 orbitals point more directly at ligands and are destabilized. e orbitals point less directly at ligands and are stabilized. x y z M L opposite splitting of octahedral field L L L Δ t < Δ o because only 4 ligands and d orbitals point between ligands

  Field, Theory, Crystal, Field theory, Octahedral, Crystal field, Octahedral field

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