AGILENT ORGANIC GPC/SEC COLUMNS

1 AGILENT ORGANIC GPC/SEC COLUMNS2 ContentsPLgel GPC COLUMNS 3 InfinityLab PlusPore COLUMNS 5 InfinityLab PolyPore 6 InfinityLab ResiPore 7 InfinityLab MesoPore 8 InfinityLab OligoPore 9PL Rapide COLUMNS 10 Narrow Bore COLUMNS 11 InfinityLab PLgel Olexis 12 PLgel MIXED COLUMNS

2 13 PLgel 20 m MIXED-A 14 PLgel 10 m MIXED-B 15 PLgel 5 m MIXED-C 16 PLgel 5 m MIXED-D 17 PLgel 3 m MIXED-E 18 PLgel MIXED-LS 19PL HFIPgel 20 EnviroPrep COLUMNS 21 PLgel Individual Pore Size COLUMNS 22 PLgel Preparative

3 COLUMNS 24 AGILENT Publications 26 AGILENT GPC/SEC Analysis systems 27 EasiCal standardsNew format shortens sample preparation time and the speed of calibration1993 PLgel COLUMNS , individual standards, and standard kitsPolymer Laboratories founded to develop market-leading products for ORGANIC GPC/SECPLgel MIXED COLUMNS , PL aquagel columnsMIXED COLUMNS improve data quality, and novel chemistries for analysis of water-soluble polymersGPC softwareDedicated software streamlines GPC/SEC calculations198119841976 PL-GPC 220 instrumentMarket-leading high temperature GPC system for even the most difficult samples at temperatures up to 220 C19993 For molecular weight separation using ORGANIC solventsRobustPLgel media is a highly cross-linked Polystyrene-Divinylbenzene (PS-DVB) gel, which offers unequalled stability for a broad range of solvents and polymer analysis has evolved, so have we.

4 Modern HPLC users can now benefit from AGILENT 's newest innovations in GPC COLUMNS , enabling drastically improved speed and resolution in a wide range of applications. ReliableFor over 40 years, AGILENT has continuously manufactured reliable, reproducible PLgel COLUMNS for critical industry Innovations InfinityLab PlusPore - for next generation fast GPC of a wide range of compounds InfinityLab PLgel Olexis - for optimized performance during high temperature analysis PLgel MIXED LS - for noise-free light scattering analysis PLgel Preparative - for fast sample preparation fractionation, and offline sure where to start? Learn more: Step-by-Step Method Development for GPC/SEC (5991-7272EN) Polymer-to-Solvent Reference Table for GPC/SEC (5991-6802EN) Instrument Setup for Fast GPC (5991-7191EN)PLGEL GPC COLUMNSThe 1260 Infinity II Multi-Detector GPC/SEC System The first choice for accurate, reproducible polymer analysis.

5 Select any combination of light scattering, viscometry and refractive index detection for absolute molecular weights and COLUMNS and EasiVial standardsNew chemistries deliver high-pore-volume materials for increased resolution, and EasiVial standards simplify calibration procedures even further2004 PLgel Olexis columnsOptimized for polyolefin analysis with highest resolution and data quality for even ultrahigh molecular weight samples20071260 Infinity Multi Detector Suite and PolarGel columnsThe 1260 Infinity MDS turns any LC into a powerful multi-detector GPC system, and PolarGel COLUMNS analyze polar samples in any solvent system2009PL MultiSolvent GPC columnsThe newest addition to the InfinityLab GPC family, offering solvent flexibility for a variety of GPC analyses all on one choice of solvent in GPC is critical to ensure the prevention of secondary interactions leading to incorrect MW measurements.

6 Analytes must have similar polarity to the solvent to prevent these find the best solvent for your samples, refer to the Polymer-to-Solvent Reference Table for GPC/SEC , publication full instructions on solvent use, refer to the GPC/SEC Column User Guide, publication 5991-3792EN Can be run at temperatures up to 220 C, and at pressures up to 150 bar Tolerate ORGANIC solvents at pH 1-14 and up to 10% water can be used in miscible ORGANIC solvents Are supplied in ethyl benzene and can be transferred between solvents for different polymer analyses without risk of degradationSolvent compatibilityPLgel column conditionsOrdering informationPLgel column accessoriesDescriptionQuantity (pk)Part removal tool for threaded COLUMNS only 1PL1310-0001 Frit (2 m) kit for threaded COLUMNS , mm id 5PL1310-0002 Frit (5 m) kit for threaded COLUMNS , mm id 5PL1310-0012 Frit (10 m) kit for threaded COLUMNS , mm id 5PL1310-0036 PLgel 10 m column repair gel 1PL1410-0101 PLgel 5 m column repair gel 1PL1410-0501 Column connecting nuts, 1/16 inch tube 5PL1310-0007 Tubing ferrules, 1/16 inch tube 5PL1310-0008 Connecting tubing, 10 cm length, inch id 10PL1310-0048 PLgel frit porosityMedia TypePorosity ( m)PLgel 3 m2 PLgel 5 m2 PLgel 10 m5 PLgel 20 m10 PLGEL GPC COLUMNSC ompatible solventsSolvent polarity (THF) (Stabilized only) (Stabilized only) ethyl ketone (MEK) (o-DCB) Trichlorobenzene (TCB) o-Chlorophenol (o-CP) Dimethyl acetamide (DMAc) n-Methyl pyrrolidone (NMP) Dimethyl sulfoxide (DMSO)

7 Dimethyl formamide (DMF )5 INFINITYLAB PLUSPORE COLUMNSNext generation GPC particles Separate many common samples in under 10 minutes High efficiencies and large pore volumes give very high resolution Optimized separation over 4 common MW rangesThe InfinityLab PlusPore family of GPC COLUMNS uses small, high efficiency media with improved pore volumes to maximize the overall separation. Multiple pore sizes are present on each PS-DVB particle to further increase efficiency, while still offering a wide MW range with no dislocations. These COLUMNS offer a substantial improvement in both speed and resolution over existing GPC technologies, without sacrificing key factors like reliability and time/minInfinityLab PolyPoreInfinityLab ResiPoreInfinityLab MesoPoreInfinityLab OligoPoreInfinityLab PlusPore calibration curvesPlusPore selection guideColumnMW Range (g/mol) (PS)Nominal Particle Size ( m)Typical efficiency (p/m)Recommended calibrantsFrit porosity ( m)

8 InfinityLab PolyPore200 to 2,000,0005>60,000 EasiCal PS-1or EasiVial PS-H2 InfinityLab ResiPoreup to 500,0003>80,000 EasiCal PS-2 or EasiVial PS-M2 InfinityLab MesoPoreup to 25,0003>80,000 Polystyrene S-L-10 Kit 2 InfinityLab OligoPoreup to 3,3006>55,000 Polystyrene S-L2-10 Kit2 AGILENT InfinityLab Maximize Your LC Workflow EfficiencyHow can you make your LC workflow more efficient, so you can spend more time on your analytical priorities? Find out with AGILENT InfinityLab an optimized portfolio of LC instruments, COLUMNS , and supplies designed to work together in perfect more at: POLYPOREU nrivalled resolution of general polymers Optimized for the separation of large polymers and broad MW distributions High efficiency particles result in shorter runs and superior resolution High performance over the widest range of MWsTypical applicationsPolystyrenes, polycarbonates, polyurethanes, polysiloxanesConditionsColumns: 2x InfinityLab PolyPore, x 300 mmEluent: TolueneFlow rate: mL/minTemperature: 60 CDetector: AGILENT 1260 Infinity II Multi Detector System Analysis of polydimethylsiloxane (PDMS)Polymethylmethacrylate in DMF025minviscometerRICharacteristicsNomi nal particle size.

9 5 mLinear MW operating range: 200 to 2,000,000 g/mol (PS equivalent)Guaranteed column efficiency: >60,000 p/mTypical pressure: 1 mL/min ( mm id): 30 bar (145 psi) per 300 mm (THF @ 25 C, TCB @ 140 C)Maximum flow rate: mm id: mL/minMaximum pressure: 150 bar (2175 psi)Maximum temperature: 150 CRecommended number of COLUMNS /set: 2x 300 mmRecommended calibrants: EasiVial PS-H for convenient 12 point calibration in three preweighed vials (2 mL vials: PL2010-0201, 4 mL vials: PL2010-0200) EasiCal PS-1 for a 10 point calibration in an easy, stir-in formatSee publication 5990-7996EN, GPC/SEC Standards Product GuideOrdering InformationDescriptionPart PolyPore, x 250 mmPL1913-5500 InfinityLab PolyPore, x 250 mmPL1513-5500 InfinityLab PolyPore, x 300 mmPL1113-6500 InfinityLab PolyPore Guard, x 50 mmPL1513-1500 InfinityLab PolyPore Guard, x 50 mmPL1113-1500 ConditionsColumns: 2x InfinityLab PolyPore, x 300 mmSample: Commercial PMMAE luent: DMF + LiBrFlow rate: mL/minTemp: 80 CInjection volume: 100 LDetector.

10 RI7 INFINITYLAB RESIPOREHigh resolution of resins and condensation polymers Optimized for the separation of medium MW polymers 3 m particles offer the highest efficiency and resolution Excellent performance over a broad MW rangeInfinityLab ResiPore COLUMNS are the ideal choice for the analysis of resins and condensation polymers with complex molecular weight distributions that include oligomer content. By combining a low 3 m particle size and high pore volume, high efficiency InfinityLab ResiPore COLUMNS offer maximum resolution of these intermediate molecular weight applicationsEpoxy resins, polyester resins, silicone fluids, polyol