MARASPERSE N-22 - POWDER

1 SECTION 1: Identification of the substance/preparation and of the Product identifierTrade name: MARASPERSE N-22 - POWDERS ynonyms:Sodium Relevant identified uses of the substance or mixture and uses advised againstRecommended uses:Binder Dispersing Details of the supplier of the safety data sheetSupplierCompany:LignoTech USA, IncAddress:100 Grand AvenueRothschild, WI 54474-1198 Country:UNITED Emergency Telephone Number+1(715)359-6544 (Emergency phone) +1(800)424-9300 (Chemtrec phone) (24h)SECTION 2: Hazards Classification of the substance or mixtureCLP Classification - otherinformation:The product does not have to be Label elementsSignal Other hazardsNuisance dust. OSHA Hazard Category: Combustible Dust. Warning. May form combustible dust concentrations in 3: Composition/information on MixturesSubstanceCAS numberEC NoREACH 91%Water7732-18-523-17-912 9%Issued: 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDER1 / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDERP lease see section 16 for the full text of R-phrases and 4: First aid Description of first aid measuresInhalation:Seek fresh :Wash out mouth thoroughly and drink 1-2 glasses of water in small contact:Wash the skin with water.

2 Remove contaminated contact:Flush with water (preferably using eye wash equipment) until irritation subsides. Seekmedical advice if symptoms Most important symptoms and effects, both acute and delayedNuisance Indication of any immediate medical attention and special treatment 5: Fire-fighting Extinguishing mediaSuitable extinguishing media:Extinguish with POWDER , foam, carbon dioxide or water extinguishingmedia:Do not use water stream, as it may spread the Special hazards arising from the substance or mixtureNote the risk of dust Advice for fire-fightersWear Self-Contained Breathing Apparatus (SCBA) with a chemical protection 6: Accidental release Personal precautions, protective equipment and emergency proceduresFor non-emergency personnel:Avoid formation of dust. Provide good Environmental precautionsAvoid unnecessary release to the environment. Prevent spillage from entering drains and/or surface Methods and material for containment and cleaning upSweep up/collect spills for possible reuse or transfer to suitable waste Reference to other sectionsSee section 8 for type of protective equipment.

3 See section 13 for instructions on 7: Handling and storage2 / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - Precautions for safe handlingWork under effective process ventilation ( local exhaust ventilation). Conditions for safe storage, including any incompatibilitiesStore in a dry, cool, well-ventilated area. Avoid accumulation of Specific end use(s)SECTION 8: Exposure controls/personal Control parametersOccupational exposure limitSubstance nameTime periodppmmg/m3 CommentRemarksNuisance dust(OSHA PELV)8h15totalNuisance dust(OSHA PELV)8h5respirableBiological threshold values:Avoid formation of Exposure controlsAppropriate engineeringcontrols:Provide good protective equipment,eye/face protection:Wear safety goggles if there is a risk of dust contact with protective equipment,skin protection:In the event of direct skin contact, wear protective gloves:Personal protective equipment,respiratory protection:Wear respiratory protective equipment with P2 filter when performing dusty work.

4 NIOSH approved dust mask 9: Physical and chemical Information on basic physical and chemical propertiesParameterValue/unitStatePowder ColourBrownOdourMildSolubilityWater propertiesOxidising propertiesParameterValue/unitRemarkspH (solution for use)8(3% sol)pH (concentrate)Not point CNot point CNot boiling point and boiling range CNot Point CNot rateNot (solid, gas)Not / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDERF lammability limitsNot limitsvol%LEL: UEL: pressurekPaNot densityNot densityNot coefficient n-octonol/water100% temperature> 400 C(for dust)Decomposition temperature> 200 CViscositycStNot thresholdppmNot Other - g/ml (bulkdensity)Combustible Dust CharacteristicsMIE: 1130 mJoule; Kst: St1 (0-200 bar*m/s); Partsize: 100% < 150 10: Stability and ReactivityNot Chemical Possibility of hazardous reactionsNone Conditions to avoidAvoid formation of dust. Avoid spark due to static Incompatible materialsStrong Hazardous decomposition productsTypical combustion 11: Toxicological Information on toxicological effectsAcute toxicity - oralSodium lignosulfonateOrganismTest TypeExposure timeValueConclusionTest methodSourceRat > 7000mg/kgBased on existing data, the classification criteria are deemed not to have been toxicity - inhalation:The product does not have to be / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - POWDERSkin corrosion/irritation:The product does not have to be eye damage/eyeirritation:The product does not have to be sensitisation orskin sensitisation:None cell mutagenicity:None properties:The product does not have to be 12.

5 Ecological ToxicitySodium lignosulfonateOrganismSpeciesExposure timeTest TypeValueConclusionTest methodSourceAcute algaeScenedesmussubspicatus24, 48, 72hEC50 > 600mg/lSimilar productAcute DaphniaDaphniamagna24, 48hEC50 > 1000mg/lSimilar productAcute fishBrachydaniorerioEC50 > 1000mg/lSimilar productNo effect on the environment. Based on existing data, the classification criteria are deemed not to have been Persistence and degradabilityPartially biodegradable BOD: 300g 02/kg ( solution) & COD: 1200g 02/kg ( solution) Bioaccumulative potentialNo bioaccumulation Mobility in soilSolubility in water: Completely Results of PBT and vPvB assessmentThe product does not contain any PBT or vPvB Other adverse effectsNone 13: Disposal Waste treatment methodsDispose of in accordance with Local Authority 14: Transport UN-No.:Not Packing group:Not UN proper shippingname:Not Environmentalhazards:Not / 6 Copyright 1995 - 2015 DGOffice A/S, : 15-05-2015 Safety Data SheetMARASPERSE N-22 - Transport hazardclass(es):Not Special precautions for Transport in bulk according to Annex II of MARPOL73/78 and the IBC codeNot Information:DOT Class 55 Lignin Pitch - Harmonized Tariff Code for 15: Regulatory Safety, health and environmental regulations/legislation specific for the substance or mixtureSpecial Provisions:ADR/RID (2007) ECHA FAQ GHS / CLP (EC NO1272/2008) GHS USA June, / limitations:Global inventory status: Australia: On AICS Australian Inventory of Chemical Substances,June 1996 Ed Canada: On DSL Supplement to Canada Gazette, Part I, January 26, 1991 China: On IECSC Inventory of Existing Chemical Substances in China, 2013 Japan: OnENCS Unlisted chemical name.

6 For ENCS chemical class or category name, refer to ENCSNo. 8-209. Korea: On ECL Korean Existing Chemicals List, January 1997, ECL Serial No.:KE-04572 Mexico: On INSQ National Inventory of Chemical Substances in Mexico, 2012 New Zealand: On NZIoC New Zealand Inventory of Chemicals, 2006 May be used as asingle component chemical under an appropriate group standard. Philippines: On PICCSP hilippines Inventory of Chemicals and Chemical Substances, 2000 Switzerland: OnSWISS Giftliste 1 (List of Toxic Substances 1), 31 May 1999, SWISS No.: G-44534 USA:On TSCA Inventory January 2015 TSCA Inventory EPA Flags: XU Exempt from Update Chemical Safety AssessmentOther Information:The product does not have to be 16: Other informationOther Information:Government regulations for use of this product are summarized below: 21 CFR -Adhesives 21 CFR ; ; ; - Paper and paperboardcomponents 21 CFR - Defoamers 21 CFR - Polymers 21 CFR Animal feed 21 CFR - Substances generally recognized as safe 40 CFR ; ; ; 21 CFR ; - Pesticides for FoodVendor notes:Information given in this safety data sheet is in accordance with our information, and to thebest of our knowledge, was correct on the last revision date.

7 Information given is intented topresent guidelines for safe handling, use, processing, storage, transport, disposal anddischarge; it is not intended to be a guarantee or quality specification. It is the responsibilityof the recipient of this safety data sheet to ensure that information given here is read andunderstood by all who use, handle, dispose of or in any way come in contact with language:GB6 / 6 Copyright 1995 - 2015 DGOffice A/S.