SAFETY DATA SHEET - CITGO

1 SAFETY DATA SHEET . F- 76 military diesel Section 1. Identification GHS product identifier : F- 76 military diesel Chemical name : Fuels, diesel , No 2. Synonyms : No. 2 Grade diesel Fuel Oil; diesel No. 2; Off-Road diesel Fuel; diesel Motor Fuel No. 2; High Sulfur diesel Fuel; HS diesel Fuel; Gas Oil (Medium); C9-C16 Petroleum Hydrocarbons. Material uses : Fuel. Code : 13176. MSDS # : 13176. Supplier's details : CITGO Petroleum Corporation Box 4689. Houston, TX 77210. Emergency telephone : Technical Contact: (800) 248-4684. number (with hours of Medical Emergency: (832) 486-4700. operation) CHEMTREC Emergency: (800) 424-9300.

2 (United States Only). Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). Classification of the : FLAMMABLE LIQUIDS - Category 3. substance or mixture ACUTE TOXICITY (inhalation) - Category 4. SKIN IRRITATION - Category 2. EYE IRRITATION - Category 2B. CARCINOGENICITY - Category 2. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous system (CNS)) - Category 2. ASPIRATION HAZARD - Category 1. AQUATIC HAZARD (LONG-TERM) - Category 2. GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Flammable liquid and vapor.

3 Harmful if inhaled. Causes skin and eye irritation. Suspected of causing cancer. May be fatal if swallowed and enters airways. May cause damage to organs through prolonged or repeated exposure. (central nervous system (CNS)). Toxic to aquatic life with long lasting effects. Precautionary statements General : diesel engine exhaust can cause upper respiratory tract irritation and reversible pulmonary effects. Long-term exposure to diesel engine exhaust may cause cancer. Do not syphon by mouth. Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version :1 1/17.

4 F- 76 military diesel Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all SAFETY precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area.

5 Avoid release to the environment. Do not breathe vapor. Wash hands thoroughly after handling. Response : Collect spillage. Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON. SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse.

6 If skin irritation occurs: Get medical attention. IF IN. EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store locked up. Store in a well-ventilated place. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Supplemental label : Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and elements receiving equipment. These alone may be insufficient to remove static electricity.

7 Do not taste or swallow. Wash thoroughly after handling. Hazards not otherwise : Static accumulating flammable liquid can become electrostatically charged even in classified bonded and grounded equipment. Sparks may ignite liquid and vapor may cause flash fire or explosion. Causes digestive tract burns. Prolonged or repeated contact may dry skin and cause irritation. Section 3. Composition/information on ingredients Substance/mixture : Substance Chemical name : Fuels, diesel , No 2. Other means of : No. 2 Grade diesel Fuel Oil; diesel No. 2; Off-Road diesel Fuel; diesel Motor Fuel No.

8 Identification 2; High Sulfur diesel Fuel; HS diesel Fuel; Gas Oil (Medium); C9-C16 Petroleum Hydrocarbons. CAS number/other identifiers CAS number : 68476-34-6. Ingredient name % CAS number Fuels, diesel , No 2 >99 68476-34-6. Benzene, trimethyl- 1-5 25551-13-7. Naphthalene - 91-20-3. biphenyl - 92-52-4. Cumene - 98-82-8. Xylene - 1330-20-7. Ethylbenzene - 100-41-4. * = Various ** = Mixture ** = Proprietary Any concentration shown as a range is to protect confidentiality or is due to process variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

9 Occupational exposure limits, if available, are listed in Section 8. Date of issue/Date of revision : 3/22/2018 Date of previous issue : No previous validation Version :1 2/17. F- 76 military diesel Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10. minutes. Get medical attention. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus.

10 If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact : Wash skin thoroughly with soap and water or use recognized skin cleanser. Remove contaminated clothing and shoes.