SAFETY DATA SHEET - Konica Minolta

1 (1 5) SAFETY data SHEETMSDS: 2013076010 USDate Prepared: 2014/1/6 Date Revised:1. Identification of the substance/mixture and of the company/undertaking2. Composition/information on ingredients30-4025-455-251-151-153. Hazards identificationColored liquid. Slight characteristic HEALTH EFFECTS:::::4. First-aid measuresNo identified health Effects /Carcinogenicity :None of the components in this material is listed by IARC, NTP orACGIH as a OVERVIEWEye Effects May cause eye and mucous membrane Effects May cause slight skin Effects May be harmful if EffectsCAS#7732-18-5107-21-156-81-5 WaterEthylene glycolGlycerinSurfactantNo exposure expected under normal conditions.

2 Large amount ofvapor or mist if inhaled, move victim to fresh air symptoms occur, get medical with water and mild soap for 15 minutes. If symptoms occur,get medical flush eyes with plenty of water for 15 minutes. Getmedical attention out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious NameDyeProduct Name: Disperse Dye Ink YellowIngredients and ConcentrationProduct Name:Identification of thesupplier:Inhalation:Skin Contact:Eye Contact:Ingestion:2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANA ddress:Charge section: TEL:+81-42-589-3739,FAX:+81-42-589-3868 May be harmful if Dye Ink YellowKonica Minolta , :------(2 5) SAFETY data SHEETMSDS: 2013076010 USDate Prepared: 2014/1/6 Date Revised:Product Name: Disperse Dye Ink Yellow5.

3 Fire-fighting measures6. Accidental release measures7. Handling and storage8. Exposure controls/personal protectionUse process enclosures or local exhaust engineering controls:Keep container tightly closed. Store in a cool and dry away from incompatible substances(See Section 10).No Conditions: SAFETY adequatecontainer materials:Technical Measures:Ventilationrequirements:Precaut ions:Precautions for safehandling:Avoid contact with eyes, skin and clothing. Wear personalprotective equipment (See Section 8). Wash thoroughly with adequate personal protective equipment(See Section 8).No spill with inert material( dry sand or earth), thenplace in a chemical waste precautions, protectiveequipment and emergency procedures:Environmental precautions:Methods and materials forcontainment and cleaning up:Water spray, dry chemical, carbon dioxide, self-contained breathing apparatus and protective clothingto prevent contact with skin and eyes.

4 Apply cooling water tosides of containers that are exposed to flames. Combat fire outof sheltered Extinguishing Media:Extinguishing Media to Avoid:Fire Fighting:HandlingStorage(3 5) SAFETY data SHEETMSDS: 2013076010 USDate Prepared: 2014/1/6 Date Revised:Product Name: Disperse Dye Ink YellowTLV-TWA TLV-STEL TWA STELN oneestablished100mg/m3[C]Noneestablished NoneestablishedNoneestablishedNoneestabl ished15mg/m3(totaldust)NoneestablishedNo neestablishedNoneestablishedNoneestablis hedNoneestablishedNoneestablishedNoneest ablishedNoneestablishedNoneestablished9. Physical and chemical propertiesNo : LiquidColor: ColoredNo point:DyeEthylene glycolGlycerinSurfactantPhysical state: LiquidSplash goggles should be protection:Not required under normal Protection:ProductOdor: Slight characteristic odorpH: No point/freezingpoint:No boiling pointand boiling range:NoneAuto-ignitiontemperature:No flammabilityor explosive limits:Not required under normal Protection:Impervious gloves should be protection:Ingredient NameACGIH OSHA-PELV apour pressure: No rate: No density: No Gravity: No :water Completely.

5 Control parametersPartition coefficient:n-octanol/water:No Protective Equipment(4 5) SAFETY data SHEETMSDS: 2013076010 USDate Prepared: 2014/1/6 Date Revised:Product Name: Disperse Dye Ink Yellow10. Stability and reactivity11. Toxicological information12. Ecological informationPersistence and degradability Readily biodegradable Daphnia acute toxicity: 48hrEC50: 10000mg/l[Daphnia magna] Algae acute toxicity: 1g/l No effect [Scenedesmus subspicatus]IngredientEthylene glycolEcotoxicity Fish acute toxicity: 24hrLC50: >5000mg/l -modified ASTM D 1345[Goldfish]Mutagenicity: Ames Test:NegativeProductNo DataSkin corrosion/irritation: None [rabbit]Serious eye damage/irritation: Minimal [rabbit]Carcinogenicity: IARC:UnlistedDyeAcute toxicity (oral):LD50: 5000 mg/kg[rat]Mutagenicity: Ames Test:Negative, Chromosomal aberration test.

6 NegativeSurfactantMutagenicity: Ames Test:NegativeSkin corrosion/irritation: Mild [rabbit]Serious eye damage/irritation: Minimal [rabbit]GlycerinAcute toxicity (oral): LD50: 12600 mg/kg[rat], LD50: 4090 mg/kg[mouse],LD50: 27000 mg/kg[rabbit], LD50: 7750 mg/kg[guinea pig]Acute toxicity (inhalation):LC50: 570 mg/m3/1h[rat]Serious eye damage/irritation: Mild [rabbit]Mutagenicity: Ames Test:Negative, Chromosomal aberration test:NegativeAcute toxicity (oral): LD50: 4700 mg/kg[rat], LD50: 7500 mg/kg[mouse]Skin corrosion/irritation: Mild [rabbit]Mutagenicity: Ames Test:NegativeIngredientEthylene glycolProductAcute toxicity (oral):LD50: 2000 mg/kg[rat]Skin sensitization: None ( data of similar product)Carbon monoxide, Carbon dioxideChemical stability:Possibility of hazardousreactions:Conditions to avoid:Incompatible materials:Hazardous (5 5) SAFETY data SHEETMSDS: 2013076010 USDate Prepared: 2014/1/6 Date Revised:Product Name: Disperse Dye Ink Yellow13.

7 Disposal considerationsDisposalmethods:14. Transport informationUNclassification UN number Proper shippingname Packing group 15. Regulatory information16. Other informationHMIS Hazard Rating :Health : 1, Flammability : 1, Reactivity : 0UN Class ------------313 ReportableIngredients Ethylene glycolSARA Title III (SuperfundAmendments andReauthorization Act) 302 Extreme HazardousSubstance Disclaimer The above information is believed to be accurate and represents the bestinformation currently available to our company. However, our company makeno warranty with respect to such information, and our company assume noliability resulting from its use. Users should make their owninvestigation to determine the suitability of the information for theirparticular HazardCategories Hazard CommunicationStandard,29 CFR This product is NOT considered hazardous under this (ComprehensiveEnvironmental ResponseCompensation and LiabilityAct) Ethylene glycol: Reportable Quantities 5000 lb(2270 kg)Persistence and degradability Readily biodegradableWhen disposing of the waste or recovered material, consult federal, state and/or localregulations for the proper disposal method.

8 Fish acute toxicity: 24hrLC50:>5000mg/l[Goldfish] Daphnia acute toxicity: 24hrEC50:>10000mg/l[Daphnia magna]GlycerinEcotoxicity(1 5) SAFETY data SHEETMSDS: 2013076020 USDate Prepared: 2014/01/06 Date Revised:1. Identification of the substance/mixture and of the company/undertaking2. Composition/information on ingredients30-4025-455-251-151-153. Hazards identificationColored liquid. Slight characteristic HEALTH EFFECTS:::::4. First-aid measuresIngestion: Wash out mouth with water. Drink one or two glasses of water. Getmedical attention immediately. ONLY induce vomiting at theinstruction of a physician. Never give anything by mouth to anunconscious : No exposure expected under normal conditions.

9 Large amount ofvapor or mist if inhaled, move victim to fresh air symptoms occur, get medical Contact: Immediately flush eyes with plenty of water for 15 minutes. Getmedical attention Contact: Wash with water and mild soap for 15 minutes. If symptoms occur,get medical Effects /Carcinogenicity :None of the components in this material is listed by IARC, NTP orACGIH as a Effects May be harmful if Effects No identified health OVERVIEWEye Effects May cause eye and mucous membrane Effects May cause slight skin be harmful if ---Glycerin 56-81-5 Surfactant ---Water 7732-18-5 Ethylene glycol 107-21-1 Substance/Mixture.

10 MixtureIngredients and ConcentrationIngredient #Product Name: Disperse Dye Ink Light Yellow2-7-2, Marunouchi, Chiyoda-ku, Tokyo, 100-7015, JAPANA ddress:Charge section: TEL:+81-42-589-3739,FAX:+81-42-589-3868 Product Name:Identification of thesupplier:Disperse Dye Ink Light YellowKonica Minolta , Inc.(2 5) SAFETY data SHEETMSDS: 2013076020 USDate Prepared: 2014/01/06 Date Revised:Product Name: Disperse Dye Ink Light Yellow5. Fire-fighting measures6. Accidental release measures7. Handling and storage8. Exposure controls/personal protectionUse process enclosures or local exhaust engineering controls:Keep container tightly closed. Store in a cool and dry away from incompatible substances(See Section 10).