Valve Application in GC - Agilent

1 GC Method Compliance and Large Valve Oven ApplicationSolution FocusedKelly BeardJune 20, 2016 Compliant MethodsCompliant MethodsJune 27, 20163 What are our options? Analyzers and Analyzer Kits High Volume Well Known Analysis Many Options Application Notes Lower Volume Usually Requires a Consultant Possible Future Analyzer, Given Acceptable Sales Quantiles Channel Partner Solutions Requires Third Party Software or Requires Third Party HardwareAnalyzers and Application KitsUpdated HPI Solution GuideSearchable, 139 pages PN: 5991-1561 ENLinks to Analyzer ChapterJanuary 2013 Analyzer Overview4 Analyzers and Application KitsJanuary 2013 Analyzer Overview5 Analyzers and Application KitsJanuary 2013 Analyzer Overview6 Analyzers and Application KitsJanuary 2013 Analyzer Overview7 Analyzers and Application KitsJanuary 2013 Analyzer Overview8 Application NotesJanuary 2013 Analyzer Overview9 Example.

2 D5769 Determination of Benzene, Toluene, Total Aromatics in Finished Gasolines by Gas Chromatography/Mass Spectrometry Fred Feyerhermdeveloped Application , via ASTM method Very successful Custom Calculations Consultant is Requited for Application Very popular lately Sales Quantities have Increased Analyzer Kit In Developed as a ResultChannel PartnerJanuary 2013 Analyzer Overview10 ASTM D6730 Standard Test Method for Determination of Individual Componentsin Spark Ignition Engine Fuels by 100-meter Capillary (with PreColumn) High Resolution Gas Chromatography Detailed Hydrocarbon Analysis Difficult Analysis with 100 s of Compounds Requires Custom Software Software is Difficult to Support via Agilent Field Resources Many Software and Third Party ProvidersChannel PartnerJanuary 2013 Analyzer Overview11 ASTM D5599 Standard Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection O-FID Analysis Requires a Custom Platinum Catalyst Requires Custom Reporting Hardware can not be Supplied by Agilent Wasson-ECE is our Partner of Choice for this Analysis with Many Years of Experience

3 On the Application . Channel PartnerJanuary 2013 Analyzer Overview12 ASTM D8003 Standard Test Method for Determination of Light Hydrocarbons and Cut Point Interalsin Live Crude Oils and Condensates by Gas Chromatography New Live Crude Oil Analysis Requires HPLIS Third Party Injection Source Intended for the introduction of pressurized liquid samples containing very polar, high boiling or high carbon number analytes Requires Custom Reporting Hardware can not be Supplied or Supported by AgilentChannel PartnerJanuary 2013 Analyzer Overview13 Reformulyzer-Hydrocarbon Group Type Analysis PAC Provided Solution Test methods : ASTM D5443, ASTM D6839, IP 566, EN ISO 22854, SH/T 0741, GB/T 28768-2012, GOST R EN ISO 22854 Intended for the introduction of pressurized liquid samples containing Extensive Hardware AdditionQuestionsJanuary 2013 Analyzer Overview14 Introducing the 7890B Large Valve Oven Isothermal Zone for Valves and Columns Temperature control: -Independent control of LVO and GC oven zones Temperature Limit: -Max 330 C( Valve and column dependent) Valve configurations: -Accommodates 4/6/10/14 port valves including Hastelloy valves Column Compatibility: -Large Mandrel: Accommodates 15 feet of 1/8 inch OD metal column -Small Mandrel.

4 Accommodates 7 Ft of 1/8 OD metal column June 27, 201615 LVO Analyzer Training6-port ValveVariable RestrictorColumn Mandrel12-port ValvesValve or Mandrel PositionIntroducing the 7890B Large Valve OvenIsothermal Zone for Valves and Columns6 Internal Positions: Valves or Columns -Up to six (6) heated Valve positions-Four (4) needle Valve positions-Uses 1 heated zoneJune 27, 201616 LVO Analyzer TrainingLarge Valve Oven Features/BenefitsFeature6 position isothermal Valve oven for actuated valves, microgasifiers, needle valves, and columns (including 1/8 in packed columns) with access to valves connections without removing actuatorsBenefitOpen configuration that allows for easy maintenance; maximizing up-time.

5 Also allows for multiple configurations for method development as well as set SP1 and configuredFeatureUse only one 7890B heated zoneBenefitCurrent multi- Valve configurations may quickly consume 6 heated zones, LVO uses 5 leaving 1 for future applicationsFeatureDual thermal zones allow for thermal isolation between column oven and LVOB enefitAbility to configure analyses that require multiple thermal zones. Can run isothermal temperatures in the LVO while temperature ramping the GC oven7890B with Large Valve OvenJune 27, 201617 LVO Analyzer TrainingFast Refinery Gas Analysis with MicropackedColumnsSimultaneous O2and H2S determination7890 GC System, LVO, Column, Sample Option 112 S/SL InletOption 210 FID with EPCO ption 220 TCD with EPCO ption 221 Left Mount TCDO ption 002 or 003 Fast OvenOption 311 and 312 CryoG3445B Option #532 June 27, 201618 LVO Analyzer TrainingPerformance FeaturesLVO RGA AnalyzersFast RGA Analyzer Total run time is 8 minutes -LVO at 70 C Hydrocarbons to C5(C6+ backflush)

6 Permanent Gases O2 and Mol%Hydrogen Sulfide500 ppmCarbonyl Sulfide300 ppmHydrogen Mol%O2, N2, CO, Mol%June 27, 201619 Fast RGA with MicropackedColumnsGC/FID/TCD/TCDM icropack System Flow DiagramMicropack LVO Plumbing June 27, 201620 LVO Analyzer TrainingFast RGA with MicropackedColumns Helium CarrierSelected Method ParametersSplit/Splitless inlet: 120 C, 100:1 splitFID (front):250 C TCD (rear):260 C He carrierRef. 30 mL/minMakeup 2 mL/minTCD (side):250 C N2 carrierRef. 45 mL/minMakeup 2 ml/min, neg. polarityMain Oven Program:60 C ( 1 min) to 80 C @ 20 C/min to 190 C @ 30 C/min Large Valve Oven: Isothermal, 65 C and 70 CJune 27, 201621 LVO Analyzer TrainingFast RGA with MicropackedColumnsAnalytical Performance Hydrocarbon Channel (FID), LVO at 70 CJune 27, 201622 LVO Analyzer TrainingFast RGA with MicropackedColumnsAnalytical Performance Permanent Gas Channel (TCD)

7 , LVO at 70 C123456 June 27, 201623 LVO Analyzer TrainingFast RGA with MicropackedColumnsAnalytical Performance Oxygen StabilityStability of Oxygen Isothermal Oven at 70 C70 C75 CStability of Oxygen Isothermal Oven at 75 CJune 27, 201624 LVO Analyzer TrainingFast RGA with Micropacked Columns Helium CarrierApplication NoteJune 27, 201625 LVO Analyzer TrainingFast Refinery Gas Analysis System Based on the Agilent 7890B GC System and G3507 ALarge Valve Oven Using Micropacked Columns Fast RGA LVO AnalyzerValue Overview Analyzer, G3445B #532 Large Valve Oven External Thermal Zone Isothermal Operation Up to 6 valves or columns Expands capability of 7890 Micropacked Columns Built for speed Rapid 8 minute cycle timeIsothermal Zone Protect temperature sensitive columns simultaneous analysis of hydrogen disulfide (H2S) and oxygen (O2) Stable response for oxygen (O2)

8 Three Channel Analytical Method simultaneous analysis of hydrogen hydrocarbons and permanent gasesSimultaneous analysis of O2and H2S <8 MinutesFebruary 2014GC/FID/MS Blood Alcohol Analyzer26 LVO Based Fast RGA with Hydrogen CarrierAnalytical Performance (G3445B, #533 Available on July 1, 2014 CPL) FID ChannelC6+June 27, 201627 LVO Analyzer TrainingFast Refinery Gas Analysis with MicropackedColumnsSimultaneous O2and H2S determination using Hydrogen Carrier Gas7890 GC System, LVO, Column, Sample Option 112 S/SL InletOption 210 FID with EPCO ption 220 TCD with EPCO ption 221 Left Mount TCDO ption 002 or 003 Fast OvenOption 311 and 312 CryoG3445B Option #533 June 27.

9 201628 LVO Analyzer TrainingOverview -GC Platforms & PositioningGas ChromatographAgilent RestrictedPage 297820 GCEntry LevelPrice/Performance6850 GCSmall footprint7890 GCHighest flexibilityIndustry leaderTechnologiesLTM /7890 GCFast heating/cooling490 Micro GCFast Gas AnalysisCompact SizeThank Solution overviewAgilent RestrictedNeophyte training Shanghai,Sep, 2007 Page 30