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Ionization Interference in Inductively Coupled Plasma ...

INDUSTRIAL MATERIALS. Ionization Interference in Inductively Coupled Plasma - Optical emission spectroscopy Yosuke MORISHIGE* and Atsushi KIMURA. Inductively Coupled Plasma -optical emission spectroscopy (ICP-OES) is widely used in various high-sensitive and high-precision elemental analysis such as environmental analysis and material analysis. Although the influence of coexisting elements on ICP-OES is known to be relatively small, in the axially viewed ICP-OES, the measurement error due to Ionization Interference could be observed depending on the combinations of coexisting elements and analyte elements. The result of the study on elemental combinations clearly shows that the occurrence of Ionization Interference can be presumed from the magnitude of Ionization potentials.

108 · Ionization Interference in Inductively Coupled Plasma-Optical Emission Spectroscopy 3.5 3 2.5 2 1.5 1 0.5 0 Coexisting element Determined concentration (µ g/ml) Cs K Na Ba Li In Al Ga Cr Ni Cu B Zn P K/3 Na/3 Ba Li Al Y Mo Pb/3 Mn Ni Cu Ge B Cd Zn Fig. 2. Influence of coexisting elements in radial view 3.5 3 2.5 2 1.5 1 0.5 0 Coexisting ...

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  Emissions, Spectroscopy, Emission spectroscopy

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