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Naming Alkenes - Vanderbilt University

Naming AlkenesSuffix: -eneMany of the same rules for alkanes apply to the parent hydrocarbon by locating the longest carbon chain that contains thedouble bond and name it according to the number of carbons with the suffix -ene. H3 CCH2CH2 CCH2CH2H3CH3 CCH2CH2 CCH2CH2H3 CParent = pentenenot hexene (does not contain double bond) Number the carbons of the parent chain so the double bond carbons have thelowest possible numbers. H3 CCH2CH2 CHCHCH31234562-hexeneb. If the double bond is equidistant from each end, number so the first substituenthas the lowest number. out the full name, numbering the substituents according to their position in thechain and list them in alphabetical the double bond by the number of the first alkene carbon. more than one double bond is present, indicate their position by using the numberof the first carbon of each double bond and use the suffix -diene (for 2 doublebonds), -triene (for 3 double bonds), -tetraene (for 4 double bonds), etc.

1. Name the parent hydrocarbon by locating the longest carbon chain that contains the double bond and name it according to the number of carbons with the suffix -ene. H 3 C CH 2 CH 2 C CH 2 H 3 C CH 2 H 3 C CH 2 CH 2 C CH 2 H 3 C CH 2 Parent = pentene not hexene (does not contain double bond) 2. a. Number the carbons of the parent chain so the ...

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