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First Order Phase Transitions

First Order Phase Transitions

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Lecture 3: First Order Phase Transitions The van der Waals equation for a gas is h PC a V2 i [V−b] DNkBT: (1) (The variable ais proportional to N2 and bto N, i.e. aDN2aNand bDNbNwith a;NbNconstants). It can be motivated by rewriting it in the form PD NkBT V−b − a V2 (2) The V−bterm comes from estimating the “free volume” available ...

  Order, Equations, Rewriting

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