Galvanic Cell Notation Example - UMKC
1 Galvanic Cell Notation • Half-cell notation – Different phases are separated by vertical lines – Species in the same phase are separated by commas • Types of electrodes ¾Active electrodes – involved in the electrode half-reaction (most metal electrodes)
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Galvanic Cell Notation Example - University of …
g.web.umkc.edu3 ¾Ecell is measured with a voltmeter ¾If the (+) terminal of the voltmeter is connected to the (+) electrode (cathode), the voltmeter shows a positive reading ¾Ecell characterizes the overall cell reaction ¾If Ecell > 0, the cell reaction is spontaneous ¾If Ecell < 0, the cell reaction is non-spontaneous ¾If Ecell = 0, the cell reaction is at equilibrium
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g.web.umkc.eduExperimental Determination of Rate Laws • Determination of reaction orders and rate constants – The initial rate method – the initial rate (Rateo) of the reaction is measured at various initial concentrations ([X]o) of the reactants aA + bB →Products Rateo = k[A]o m[B] o n →If [A]o is increased by a factor, f, while [B]o is kept constant:
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