Thin Film Optics - Macleod

1 1 Macleod thin film OpticsA light waveis a propagating electromagnetic disturbance. The electromagnetic nature of li hbli h db Cl k lli h 19thbldhlight was established by James Clerk Maxwell in the 19thcentury but already the wave nature had been established and interferencewas well effects we are interested in are linear. Linear means that if we have two separate stimuli and two separate responses then the response to the sum of the two stimuli will be the sum of the separate responses. The important implication is that we can then break any arbitrary light wave into a set of simpler components and follow them separately. Usuallywewilluseasetofplaneharmonic(ormo nochromatic)wavesthatwecalltheUsually we will use a set of plane harmonic (or monochromatic) waves that we call the spectrum. Fourier theory allows us to do this theoretically but there are also all kinds of techniques that permit us to perform the decomposition experimentally.

2 Each spectral element, or component, has a sinusoidal profile and can then be treated separately. We usually assume in our calculations a continuous spectrum of equal energy components and we do this more or less automatically without really thinking about linear media the frequency of the wave remains constant but traditionally we have always used wavelength to characterize the wave. Since the velocity varies with the medium, but is always constant in vacuo, the vacuum wavelength is used. Then the actual wavelength is /n where is the vacuum wavelength and nthe refractive use the term polarization to describe the direction of the electric and magnetic fields. Plane or linear polarization is most common and implies that the direction remains constant as the wave propagates although, of course, it reverses during each half cycle of the oscillation. Polarization becomes important when we deal with coatings at oblique thin film OpticsInterference is simply the addition of the fields of the various waves involved.

3 If it involves two waves that are planeharmonicofidentical frequency and polarization (that is the orientation of the fields) and are propagating in the same direction, then, if they are coincident in phase, the resultant amplitude is the sum of the individual amplitudes, and we call this constructive interference. If the fields are in antiphase, then the amplitudes subtract, and we call this destructive. These are the two extreme thin film OpticsMost optical systems consist, at least partly, of a series of optical surfacesformed in some suitable material. Their shape is chosen correctly to manipulate the light. However it is rare to find that the specularproperties(mirror like properties obeying the law of reflection and the law of refraction)that are determined by the optical properties of the medium and of the worked material, are acceptable. Modificationof these properties is the primary function of an optical coating.

4 However, since the coating is normally on the outside of the component it is often expected to perform other functions like limiting corrosion and increasingabrasionresistance Thecoatingusuallyconsistsofoneormorethin filmsofincreasing abrasion resistance. The coating usually consists of one or more thin films of material with composition and thickness chosen to give the correct optical properties through a mixture of interference and the natural optical properties of the thin film OpticsCoatings are usually manufactured by condensationof a suitable vapor undervacuum. The different processes vary in the way in which the vapor is produced. In thermal evaporation the material is heated until it boils or sublimes. In sputtering it is produced by bombarding a target by energetic ions. Machines are complex and expensive. Because of this cost, and because the coating process is often the final one for an already expensive component, yield is of great thin film OpticsMirrors were probably the earliest optical instruments.

5 They existed all over the world and date back to prehistory. Lenses came a little later and, in the beginning, were used mainly as burning glasses. Interference colors were possibly recognized because there are many examples in nature, but the mechanism was neither known nor studied. The ancients divided materials intoopaquematerials that simply reflected, and materials that transmitted light to some thin film OpticsWe usually classifyour materials as metallic or dielectric. Metallic materials transmit little, unless very thin , and usually reflect quite strongly. Dielectric materials are essentially transparent. In thin film Optics we will usually include semiconductors in the classification of dielectric. The transparent dielectrics support interference in thin films. The short wave optical properties are dominated by electrons. The positively charged parts of molecules become important further into the thin film OpticsImagine a dielectric substrate carrying a dielectric filmin an incident medium also of dielectric material.

6 The film will support multiple beam interference as illustrated. Let the film be exceedingly thin so that the reflectance is exactly what we expect from an uncoated surface but the multiple beams still exist in the film and are adding up to that reflectance. Now let the thickness of the film be increased by one half wave. The first beam returning to the front surface now has an increase in its path of one wavelength and so the earlier phase condition is undisturbed. The next beam will acquire an extra two wavelengths and soon Itiseasytoseethatallthephaseconditionsar ecompletelyundisturbed Sincethereso on. It is easy to see that all the phase conditions are completely undisturbed. Since there is no loss, the interference condition is identical to that of the vanishingly thin layer so that a half wave thickness of material, or a whole number of half waves, yields the reflectance of the uncoated substrate.

7 Halfway between the half waves, when the film is an odd number of quarter waves thick, the phase condition is perturbed to a maximum extent and so there is a significant change in reflectance. The formulae for reflectance in both cases are shown. They represent the extreme interference conditions. Other thicknesses give results in between these two thin film OpticsMost optical coatings have more than one layer. Some have hundreds of layers. The interferencecalculations in such cases can be very complicated and are invariably carried out these days by computer. But it was not always so and much use is still made of quarterwaveand halfwavefilms because they are straightforward to understand and they represent the extreme interference thin film OpticsSimpleoptical surfaces reflect a portion of the light. This can be a problem because not only is the desired light reduced, but also the reflected light is not lost, but just goes somewhere else.

8 Somewhere else can often be the image plane, where it causes ghost images and veiling glare. Most simple optical surfaces, therefore, are treated with a antireflection coating. The least complex is a quarterwaveof magnesium fluoride that reduces the reflectance of glass as shown. Ideally we would like a material of still lower index but magnesium fluoride is the best we have. In very simple systems this single layer canoftenbeenoughandsothiscoatingisstillp roducedonanenormousscaleHowevercan often be enough and so this coating is still produced on an enormous scale. However more demanding systems require better performance and two common multilayer coatings are also shown. The four layer one is usually preferred because it uses two materials only. In practice the layer thicknesses in the four layer are adjusted very slightly from the values shown to optimize the performance. These coatings are intended for the visible region, 400nm to 700nm.

9 Antireflection coatings are required and manufactured over the whole optical spectrum. The greater the region over which reflection reduction is required, the more complex and difficult the design and the manufacture, and so the region of best performance is invariably limited to some thin film OpticsParticularlyin Europe and in Asia, spectacle lenses are usually antireflected. This reduces glare, especially in night driving, but also avoids the flare that is often seen from uncoated spectacles and masks the eyes in a photograph. Such effects become still more acute with the high index plastic lenses, like polycarbonate, that are gradually replacing the lower index materials. The usage in the United States is increasing, but is still lagging behind other regions in uptake. Here we have a demonstration of an antireflection coating on a blank lens, but, so that the performance can be readily gauged, limited in its coverage to thelogoofthecompanythatproducedit Thereissomeresidualcolorthat strictlythe logo of the company that produced it.

10 There is some residual color that, strictly speaking, is a performance defect but is presented by ophthalmic companies as a feature. The color has become an important fashion statement that is actually strongly desired by the thin film OpticsHere we have an antireflection coating on the objectives of a binocular telescope. This particular coating is known as a ruby coating and in display units in stores there is often a spotlight to illuminate the coating that then appears to glow and look very powerful. The ruby color is produced intentionally in the design that is actually more complicated than a simple antireflection coating. It is applied for two main reasons. One is connected with sales, because the ruby coating seems more scientific and impressive than a less colorful one. Another is that the spectral range is reduced and so the requirements on chromatic aberrationrelaxed High endbinocularshaveabroaderandlessspectacu larcoatingasdoaberration relaxed.