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Jahn-Teller Effect - Dalal Institute
CFSE due to distortion = Energy of the distorted complex (E2) − Energy of the complex without distortion (E1) E1o) E1o E2o – δ2/3) E2o – δ2/3 CFSE due to distortion = E2 – E1 = –δ2/3 Hence, the crystal field stabilization due to z-out distortion is –δ1/3. Moreover, it is worthy to note that this
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π-Bonding and Molecular Orbital Theory
www.dalalinstitute.comHence, the crystal field splitting Δ o increases and the bond between the ligand and the metal strengthens when metal to ligand bonding takes place. 3. When ligand π-orbitals are empty as well as filled: There are many ligands, like I–, which have both filled p-orbitals as well as vacant d-orbitals of π symmetry.
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Molecular Orbital Theory – Octahedral, Tetrahedral or ...
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