Transcription of Zinc-EDTA Titration
1 Zinc-EDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. What is pZn at the equivalence point? Log Kf for the ZnY2- complex is Both solutions are buffered to a pH of using a ammonia Corn Chem M3LC Spring 2013We use an ammonia buffer solutionfor a Y4- = at pH = product Ksp = 10 17Zn2+ + 2OH- Zn(OH)2(s)Ksp = [Zn2+][OH -]2At pH=10, [Zn2+] = ??Zinc HydroxideSolubility product Ksp = 10 17Zn2+ + 2OH- Zn(OH)2(s)Ksp = [Zn2+][OH -]2At pH=10, [Zn2+] = Ksp /[OH -]2 Zinc HydroxideSolubility product Ksp = 10 17Zn2+ + 2OH- Zn(OH)2(s)Ksp = [Zn2+][OH -]2At pH=10, [Zn2+] = Ksp /[OH -]2 Zinc Hydroxide= ( 10 17) /( 10 4)2= 10 9 M This is the maximum free Zinc Buffer SolutionAt pH=10, [NH3] = ?
2 ?[NH3]total = NH3 + H2O <=> NH4+ + OH -pKb = Buffer SolutionAt pH=10:[NH3]total = NH3 + H2O <=> NH4+ + OH -[NH3] = MpKb = - Ammonia ComplexationAt [NH3] = , Zn2+ = x 10-5 Zinc - Ammonia ComplexationAt a TOTAL Zinc concentration of x 10-4 M:[Zn2+] = Zn2+ [Zn2+]tot [Zn2+] = ( x 10-5)( x 10-4)[Zn2+] = x 10-9 MTherefore: no precipitation!EDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. What is pZn at the equivalence point? Log Kf for the ZnY2- complex is Both solutions are buffered to a pH of using a ammonia alpha fraction for Y4- is at a pH of alpha fraction for Zn2+ is x more, with feeling:EDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution.
3 Total moles of Zinc = ??EDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. Total moles of Zinc = ( x 10-4 M)( )= x 10-6 molesEDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. Total moles of Zinc = x 10-6 molesEquivalence point volume = ?? EDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. Total moles of Zinc = x 10-6 molesEquivalence point volume = EDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution.
4 Total moles of Zinc = x 10-6 molesEquivalence point volume = [ ZnY2- ] = ??EDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. Total moles of Zinc = x 10-6 molesEquivalence point volume = [ ZnY2- ] = x 10-5 MWe assume a stoichiometric Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. Total moles of Zinc = x 10-6 molesEquivalence point volume = [ ZnY2- ] = x 10-5 M[ Zn2+ ] = ??[ ZnY2- ] = x 10-5 MWe assumed a stoichiometric reaction.
5 But actually, there is a little bit of free (uncomplexed) EDTA and free (uncomplexed) Zinc in solution.[ ZnY2- ] = x 10-5 MWe assumed a stoichiometric reaction. But actually, there is a little bit of free (uncomplexed) EDTA and free (uncomplexed) Zinc in solution. Zn2+ = x 10-5 Log Kf = Y4- = [ ZnY2- ] = x 10-5 MWe assumed a stoichiometric reaction. But actually, there is a little bit of free (uncomplexed) EDTA and free (uncomplexed) Zinc in x 10-8 MEDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution.
6 Total moles of zinc = x 10-6 molesEquivalence point volume = [ ZnY2- ] = x 10-5 x 10-8 MEDTA Titration You would like to perform a Titration of mL of a x 10-4 M Zn2+ solution with a x 10-4 M EDTA solution. Total moles of zinc = x 10-6 molesEquivalence point volume = [ ZnY2- ] = x 10-5 M= ( x 10-5) ( x 10-8 M)[ Zn2+ ] = x 10-13 MpZn = are done! x 10-6 M
